This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.
Beilstein J. Org. Chem. 2014, 10, 1681–1685, doi:10.3762/bjoc.10.176
Graphical Abstract
Figure 1: Structures of trachycladine A and B.
Figure 2: Retrosynthetic analysis of trachycladines A and B.
Scheme 1: Synthesis of 5-deoxy-1-O-acetyl-2,3-di-O-benzoyl-2-C-β-methyl-D-ribofuranose (4). Reagents and cond...
Figure 3: The X-ray crystal structural of 1-O-methyl-3-O-(2,4-dichlorobenzyl)-5-deoxy-α-D-ribofuranose (9).
Scheme 2: Synthesis of trachycladine B (2). Reagents and conditions: (a) i. N,O-Bis(trimethylsilyl)acetamide ...
Scheme 3: Synthesis of trachycladine A (1). Reagents and conditions: (a) DBU, TMSOTf, CH3CN, 86%; (b) NH3 sat...
Beilstein J. Org. Chem. 2014, 10, 276–281, doi:10.3762/bjoc.10.23
Figure 1: Structure of decandrinin (1).
Figure 2: Selected 1H–1H COSY and HMBC correlations for decandrinin (1).
Figure 3: Diagnostic NOE interactions for decandrinin (1, B97D/TZVP-optimized structure): arbitrarily the 5R,9...
Figure 4: Determination of the absolute configuration of decandrinin (1) by comparing the calculated CD spect...
Scheme 1: Proposed biosynthetic pathway for decandrinin (1).